CO2 Adsorption in a Robust Iron(III) Pyrazolate‐Based MOF: Molecular‐Level Details and Frameworks Dynamics From Powder X‐ray Diffraction Adsorption Isotherms

• DOI: 10.1002/adma.202209907
• Publication Date: 2023-02-03T19:58:10Z
• Authors: Rebecca Vismara; Stephanie Terruzzi; Angelo Maspero; Toni Grell; Filippo Bossola; Angelo Sironi; Simona Galli; Jorge A. R. Navarro; Valentina Colombo
• Keywords: Powder Diffraction

Understanding adsorption processes at the molecular level, with multi-technique approaches, is nowadays frontier of porous materials research. In this work it shown that a proper data treatment, in situ high-resolution powder X-ray diffraction (HR-PXRD) variable temperature and gas pressure can reveal atomic details accommodation sites, framework dynamics as well thermodynamic information (isosteric heat adsorption) CO