Asymmetric Total Synthesis of Cylindrocyclophanes A and F through Cyclodimerization and a Ramberg–Bäcklund Reaction

• DOI: 10.1002/ange.201003500
• Publication Date: 2010-07-12T11:12:50Z
• Authors: K. C. Nicolaou; Ya‐Ping Sun; Henry Korman; David Sarlah
• Keywords: Schema (genetic algorithms)

Zwei bilden einen Kreis: Eine Ramberg-Bäcklund-Reaktion wurde für den Aufbau des makrocyclischen Kohlenstoffgerüsts der marinen Naturstoffe Cylindrocyclophan A und F in einer asymmetrischen Synthese durch Kopf-Schwanz-Dimerisierung genutzt (siehe Schema). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents peer-reviewed, but not copy-edited or typeset. They made available submitted by the authors. Please note: The publisher is responsible for content functionality any supporting information supplied Any queries (other than missing content) should be directed corresponding author article.