Rational Construction of an Extrinsic Porous Molecular Crystal with an Extraordinary High Specific Surface Area

• DOI: 10.1002/anie.201201174
• Publication Date: 2012-04-03T15:41:16Z
• Authors: Michael Mastalerz; Iris M. Oppel
• Keywords: Triptycene; Bar (unit); Crystal (programming language); Derivative (finance)

Small molecule, large surface area: A rigid triptycene derivative self-assembles by hydrogen bonds to a porous crystal with one-dimensional channels of about 14 Å diameter. Solvents in the can be removed generate an extrinsic material specific BET area 2796 m2 g−1. Furthermore, gases selectively adsorbed within pores at 1 bar. Detailed facts importance specialist readers are published as "Supporting Information". Such documents peer-reviewed, but not copy-edited or typeset. They made available submitted authors. Please note: The publisher is responsible for content functionality any supporting information supplied Any queries (other than missing content) should directed corresponding author article.