Copper‐Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

• DOI: 10.1002/anie.201207148
• Publication Date: 2012-10-08T10:37:03Z
• Authors: Tetsuaki Fujihara; Yosuke Tani; Kazuhiko Semba; Jun Terao; Yasushi Tsuji
• Keywords: 01 natural sciences; 0104 chemical sciences

AbstractThe reaction proceeds regioselectively, the major isomers (IV) are isolated in good to high yields.