ChemInform Abstract: Iron Catalyzed Asymmetric Oxyamination of Olefins.

• DOI: 10.1002/chin.201305096
• Publication Date: 2013-02-13T08:31:17Z
• Authors: Kevin S. Williamson; Tehshik P. Yoon
• Keywords: Oxazoline; Sulfonyl

Abstract N‐Sulfonyl oxaziridines react with terminal alkenes in the presence of a novel iron(II)/chiral bis(oxazoline) catalyst to give oxazolidines excellent regio‐ and diastereoselectivity (cis:trans <10:1), up 95% enantioselectivity.