Di(1‐naphthyl) methanol ester of carboxylic acids for absolute stereochemical determination

01 natural sciences 0104 chemical sciences
DOI: 10.1002/chir.22775 Publication Date: 2017-11-08T08:46:04Z
ABSTRACT
AbstractThe absolute stereochemistry of chiral carboxylic acids is determined as a di(1‐naphthyl)methanol ester derivative. Computational scoring of conformations favoring either P or M helicity of the naphthyl groups, capable of exciton‐coupled circular dichroic coupling, leads to a predicted stereochemistry for the derivatized carboxylic acids.
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