Problem of intermediate reaction products of silicon with methyl chloride

• DOI: 10.1007/bf00854124
• Publication Date: 2004-12-24T05:24:05Z
• Authors: V. I. Zubkov; S. A. Golubtsov; K. A. Andrianov; M. V. Tikhomirov
• Keywords: 01 natural sciences; 0104 chemical sciences

1. The prior chlorination of silicon leads to a reduction in the start of the reaction of silicon with methyl chloride by ∼300°. 2. The reaction of the chlorinated silicon with methyl chloride leads to a loss in the activity of the silicon surface, which is explained by the consumption of the intermediate products that are formed on the silicon surface during chlorination. A second chlorination of the silicon restores the activity.