Synthesis and characterization of multipyrene-modified platinum acetylide oligomers

• DOI: 10.1007/s00706-012-0892-4
• Publication Date: 2013-01-08T23:23:51Z
• Authors: Nai-Wei Wu; Jing Zhang; Cui-Hong Wang; Lin Xu; Hai-Bo Yang
• Keywords: 01 natural sciences; 0104 chemical sciences

A series of new multipyrene-modified platinum acetylide oligomers were successfully synthesized utilizing the coupling reaction of trans-Pt complexes with C–H bonds in alkynes as the key step. These new conjugated oligomers were characterized by multinuclear NMR (1H, 13C, and 31P) and mass spectrometry (MALDI-TOF–MS). Preliminary spectroscopic studies of these oligomers were also carried out.