An Experimental and Theoretical Study of Cu0.2Zn0.8S Thin Film Grown by Facile Chemical Bath Deposition As an Efficient Photosensor

• DOI: 10.1007/s11664-018-6491-3
• Publication Date: 2018-07-19T00:57:58Z
• Authors: Ghamdan M. M. Gubari; S. M. Ibrahim Moh...; Nanasaheb P. Huse; Avinash S. Dive; Ramphal Sharma
• Keywords: Chemical bath deposition

We have successfully deposited Cu0.2Zn0.8S thin films onto a glass substrate by facile chemical bath deposition at 60°C. The structural, morphological, optical, electrical and electronic properties of the as-grown Cu0.2Zn0.8S thin film were studied. The x-ray diffraction pattern confirmed the formation of the Cu0.2Zn0.8S composition when compared with standard JCPDS card. The Raman spectrum shows a major peak at 470 cm−1 along with few other which are attributed to Cu0.2Zn0.8S phase. The field emission scanning electron microscopy result shows the uniform growth of material over the entire glass substrate with dense morphology containing irregularly shaped grains. From the optical absorption spectrum, a clear band edge around ∼ 430 nm was observ,ed which results in a wide energy band gap of ∼ 2.9 eV. The obtained band gap is in good agreement with the earlier reports. The electrical properties were measured at room temperature in the voltage range ± 2 V and showed a drastic enhancement in current under light illumination with the highest photosensitivity of ∼ 91% for 260 W. The electrical properties suggest its promising candidature for optoelectronic devices. The electronic properties like band structure, the partial and total density of states were studied with density functional theory formalism with generalized gradient approximation which suggests that Cu0.2Zn0.8S is a direct band semiconductor with a band gap of ∼ 1.64 eV.