Boron-doped microporous nano carbon as cathode material for high-performance Li-S batteries

• DOI: 10.1007/s12274-016-1303-7
• Publication Date: 2016-11-07T14:07:51Z
• Authors: Feng Wu; Ji Qian; Weiping Wu; Yusheng Ye; Zhiguo Sun; Bin Xu; Xiaoguang Yang; Yuhong Xu; Jiatao Zhang; Renjie Chen
• Keywords: TA; 02 engineering and technology; 0210 nano-technology; 7. Clean energy

In this study, a boron-doped microporous carbon (BMC)/sulfur nanocomposite is synthesized and applied as a novel cathode material for advanced Li-S batteries. The cell with this cathode exhibits an ultrahigh cycling stability and rate capability. After activation, a capacity of 749.5 mAh/g was obtained on the 54th cycle at a discharge current of 3.2 A/g. After 500 cycles, capacity of 561.8 mAh/g remained (74.96% retention), with only a very small average capacity decay of 0.056%. The excellent reversibility and stability of the novel sulfur cathode can be attributed to the ability of the boron-doped microporous carbon host to both physically confine polysulfides and chemically bind these species on the host surface. Theoretical calculations confirm that boron-doped carbon is capable of significantly stronger interactions with the polysulfide species than undoped carbon, most likely as a result of the lower electronegativity of boron. We believe that this doping strategy can be extended to other metal-air batteries and fuel cells, and that it has promising potential for many different applications.