Room temperature synthesis of needle-shaped ZnO nanorods via sonochemical method

• DOI: 10.1016/j.apsusc.2007.03.060
• Publication Date: 2007-04-06T11:55:17Z
• Authors: Rizwan Wahab; S.G. Ansari; Young-Soon Kim; Hyung-Kee Seo; Hyung-Shik Shin
• Keywords: Nanorod; Wurtzite crystal structure; Sonication; Zinc hydroxide; Hexagonal phase; Sodium hydroxide

Abstract Single crystalline needle-shaped zinc oxide nanorods were synthesized via sonochemical methods using zinc acetate dihydrate and sodium hydroxide at room temperature. Morphological investigation revealed that the nanoneedles are of hexagonal surfaces along the length. The typical diameter and length vary from 120 to 160 nm and 3 to 5 μm, respectively. Sonication time appears to be a critical parameter for the shape determination. Detailed structural characterization confirmed that the nanorods are single crystalline with wurtzite hexagonal phase. A standard peak of zinc oxide was observed at 520 cm−1 from the Fourier transform infrared spectroscopy. The ultra-violet visible and room temperature photoluminescence (PL) spectroscopic results demonstrate that the synthesized material has good optical properties.