A facile modification of g-C3N4 with enhanced photocatalytic activity for degradation of methylene blue

• DOI: 10.1016/j.apsusc.2013.05.127
• Publication Date: 2013-06-03T17:32:47Z
• Authors: Fei Chang; Yunchao Xie; Chenlu Li; Juan Chen; Jieru Luo; Xuefeng Hu; Jiaowen Shen
• Keywords: 01 natural sciences; 0104 chemical sciences

In this investigation, a facile modification of g-C3N4 through co-pyrolysis of melamine and sodium nitrate or potassium nitrate was reported and the as-synthesized samples were characterized by a collection of techniques, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV-vis diffuse reflectance spectroscopy, nitrogen adsorption-desorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and elemental analysis. Based upon the analysis, we speculated that the g-C3N4 framework was partially destroyed to produce cyano-containing fragments, which resulted into the variation of physical and optical properties, further affecting the adsorption and photocatalytic performance of g-C3N4 on the dye methylene blue. Furthermore, we found that nitrate anions rather than sodium or potassium ions had important effect on the structure and photocatalytic performance of g-C3N4. In addition, the photocatalysis mechanism and reusability test were also investigated and discussed in the study. (C) 2013 Elsevier B.V. All rights reserved.