Improvement in photocatalytic H2 evolution over g-C3N4 prepared from protonated melamine

• DOI: 10.1016/j.apsusc.2014.01.008
• Publication Date: 2014-01-11T00:31:40Z
• Authors: Yujiao Zhong; Zhiqiang Wang; Jianyong Feng; Shicheng Yan; Haitao Zhang; Zhaosheng Li; Zhigang Zou
• Keywords: Specific surface area

Abstract Porous g-C 3 N 4 (pm-g-C 3 N 4 ) samples were prepared by sintering protonated melamine. Photocatalytic activities for H 2 production over the g-C 3 N 4 samples were evaluated under visible-light irradiation. Specific surface areas and condensation degree of the g-C 3 N 4 samples prepared from protonated melamine turn larger as the calcination temperatures increase (400 °C, 450 °C, 500 °C, 550 °C, and 580 °C for 1 h). Also, their bandgaps are narrowed and PL peak red shifts, and thus their photocatalytic activities are enhanced. Compared with the reference g-C 3 N 4 samples synthesized by sintering melamine without any protonation (m-g-C 3 N 4 ), the pm-g-C 3 N 4 samples exhibit better photocatalytic performances, owing to larger specific surface area, less recombination of photogenerated carriers and higher degree of condensation. By optimizing the preparation parameters and the amount of Pt cocatalyst, the highest hydrogen evolution rate of 417 μmol h −1 g −1 was achieved over the pm-g-C 3 N 4 samples synthesized at 550 °C for 2 h, when irradiated by 300-W Xe lamp with a cutoff filter ( λ ≥ 420 nm).