Cationic compositional optimization of CuIn(S 1-y Se y ) 2 ultra-thin layers obtained by chemical bath deposition

• DOI: 10.1016/j.apsusc.2017.01.217
• Publication Date: 2017-01-27T12:46:49Z
• Authors: S. Lugo; Y. Sánchez; M. Espíndola; F. Oliva; V. Izquierdo-Roca; Y. Peña; E. Saucedo
• Keywords: Cationic polymerization; Chemical bath deposition; Deposition

Abstract This paper reports the synthesis of CuIn(S 1-y Se y ) 2 (CISSe) (y = 0.84–0.93) ultra-thin films prepared by a sequential process based on the chemical bath deposition of In 2 S 3 /Cu 2-x S precursor layers, followed by annealing under selenium atmosphere. The layers were synthesized varying the [Cu]/[In] ratio from 0.8 to 1.26 and the impact of this variation on the surface region of the ultra-thin absorbers is analyzed for each composition. Through a first optimization of this parameter, we achieved power conversion efficiencies up to 2.7% with open circuit voltage of 334 mV, short circuit current density of 16.1 mA/cm 2 and fill factor of 50.9% using a Glass/Mo/CISSe/CdS/i-ZnO/ZnO:Al solar cell structure, for a 600 nm thick absorber annealed at relatively low temperature (450 °C/30 min). This demonstrates that this new synthesis method has potential as a low-cost alternative for CISSe solar cells production.