CaFeAl mixed oxide derived heterogeneous catalysts for transesterification of soybean oil to biodiesel

• DOI: 10.1016/j.biortech.2015.02.046
• Publication Date: 2015-02-17T22:18:42Z
• Authors: Yongsheng Lu; Zaiwu Zhang; Yunfeng Xu; Qiang Liu; Guangren Qian
• Keywords: Soybean oil; Mixed oxide

CaAl layered double oxides (LDO) were prepared by co-precipitation and calcined at 750°C, and then applied to biodiesel production by transesterification reaction between methanol and soybean oil. Compared with characteristics of CaFe/LDO and CaAl/LDO, CaFeAl/LDO had the best performance based on prominent catalytic activity and stability, and achieved over 90% biodiesel yield, which stayed stable (over 85%) even after 8 cycles of reaction. The optimal catalytic reaction condition was 12:1M-ratio of methanol/oil, reaction temperatures of 60°C, 270rpm stirring rate, 60min reaction time, and 6% weight-ratio of catalyst/oil. In addition, the CaFeAl/LDO catalyst is insoluble in both methanol and methyl esters and can be easily separated for further reaction, turning it into an excellent alternative for biodiesel synthesis.