Synthesis and characterization of B-doped TiO2 and their performance for the degradation of metoprolol

• DOI: 10.1016/j.cattod.2014.09.030
• Publication Date: 2014-11-01T08:50:11Z
• Authors: Rodrigo Pereira C...; Renato Falcao Dantas; Bernardí Bayarri; Oscar González; Jaime Giménez; Santiago Esplugas; Amilcar Machulek
• Keywords: Photodegradation; Rutile; Specific surface area

Abstract Pure and B-doped TiO 2 photocatalysts were synthesized by sol–gel method. Boric acid was used as boron source and titanium tetra-isopropoxide as TiO 2 precursor. Nominal boron/titania proportions were in the range 0–9% (w/w). The powder was characterized by X-ray diffraction (XRD), scanning and transmission electron microscopy (SEM and TEM), UV–vis absorption spectra, BET specific surface area, X-ray photoelectron spectroscopy (XPS) and zeta potential. The β-blockers are pharmaceuticals frequently detected in waters. Among these β-blockers, metoprolol (MET) is one of the most commonly used for the treatment of a variety of cardiovascular diseases, thus being necessary the search for methods able to remove it. In this context, the photocatalytic reactivity of the synthesized catalysts was evaluated by its use in MET photodegradation using a solar simulator with xenon lamp as irradiation source. Results showed that the 5% (w/w) B-doped TiO 2 exhibited greater photodegradation (70% MET removal) than pure TiO 2 (48% MET removal). Some factors were responsible for the photocatalytic performance of B-doped TiO 2 which include the high surface area, mesoporous structure, anatase–rutile crystalline structure, formation of Ti(III), introduction of boron as a B–O–Ti species and uniformity in particles surface size.