One step from nanofiber to functional hybrid structure: Pd doped ZnO/SnO2 heterojunction nanofibers with hexagonal ZnO columns for enhanced low-temperature hydrogen gas sensing

• DOI: 10.1016/j.ceramint.2021.02.085
• Publication Date: 2021-02-17T11:16:11Z
• Authors: Kelin Hu; Feipeng Wang; Yuyang Yan; Hongcheng Liu; Zijia Shen
• Keywords: 02 engineering and technology; 0210 nano-technology

Abstract In this paper, a novel hybrid structure of Pd doped ZnO/SnO2 heterojunction nanofibers with hexagonal ZnO columns was one step synthesized from electrospun precursor nanofibers. Due to the synergistic effect of hexagonal ZnO, SnO2 and Pd, the structure exhibited excellent hydrogen (H2) gas sensing properties. At low-temperature of 120 °C, the response (Ra/Rg) to 100 ppm H2 gas exceeded 160, the response/recovery time was only 20 s and 6 s respectively and the limit of detection was only 0.5 ppm. Meanwhile, it also had good selectivity for H2 gas and excellent linearity. In addition, the materials were characterized by XRD, FESEM, HRTEM, XPS, and the synthesis mechanism and gas sensing mechanism were proposed.