Assessing nitrate groundwater hotspots in Europe reveals an inadequate designation of Nitrate Vulnerable Zones

• DOI: 10.1016/j.chemosphere.2024.141830
• Publication Date: 2024-03-27T19:41:29Z
• Authors: J. Serra; C. Marques-dos-Sa...; J. Marinheiro; S. Cruz; M.R. Cameira; W. de Vries; T. Dalgaard; N.J. Hutchings; M. Graversgaard; F. Giannini-Kurina; L. Lassaletta; A. Sanz-Cobeña; M. Quemada; E. Aguilera; S. Medinets; R. Einarsson; J. Garnier
• Keywords: Europe; Water Pollutants, Chemical/analysis; Nitrates; Life Science; Nitrates/analysis; Groundwater; 01 natural sciences; Environmental Monitoring/methods; Water Pollutants, Chemical; Environmental Monitoring; 0105 earth and related environmental sciences

Monitoring networks show that the European Union Nitrates Directive (ND) has had mixed success in reducing nitrate concentrations in groundwater. By combining machine learning and monitored nitrate concentrations (1992-2019), we estimate the total area of nitrate hotspots in Europe to be 401,000 km2, with 47% occurring outside of Nitrate Vulnerable Zones (NVZs). We also found contrasting increasing or decreasing trends, varying per country and time periods. We estimate that only 5% of the 122,000 km2 of hotspots in 2019 will meet nitrate quality standards by 2040 and that these may be offset by the appearance of new hotspots. Our results reveal that the effectiveness of the ND is limited by both time-lags between the implementation of good practices and pollution reduction and an inadequate designation of NVZs. Substantial improvements in the designation and regulation of NVZs are necessary, as well as in the quality of monitoring stations in terms of spatial density and information available concerning sampling depth, if the objectives of EU legislation to protect groundwater are to be achieved.