Physico-chemical properties of γ-irradiated International Simple Glass (ISG) nuclear waste simulants with low levels of iron impurities

• DOI: 10.1016/j.chphi.2023.100233
• Publication Date: 2023-05-23T22:06:34Z
• Authors: José A. Jiménez; Charles L. Crawford; Robert J. Lascola; Jonathan H. Chris...; Bryan J. Foley
• Keywords: Borosilicate glass; Chemistry; Chemical properties; Physical properties; Gamma radiation; Physics; QC1-999; 02 engineering and technology; 0210 nano-technology; Nuclear waste vitrification; QD1-999

The effect of γ-irradiation on physico-chemical properties of International Simple Glass (ISG) nuclear waste glass simulants with low iron impurities was investigated. The study was performed on glasses produced by Corning Inc. (named ISG-1, ISG-2) following a 0.95 MGy dose. Fourier-transform infrared and Raman spectroscopy, chemical durability tests, dilatometry, differential scanning calorimetry, electron paramagnetic resonance (EPR), optical absorption, and photoluminescence (PL) spectroscopy appraisals were done in comparison with pristine glasses. The data indicated that structural, chemical, and thermal properties were not significantly altered following γ-ray exposure. EPR spectroscopy showed radiogenic signatures from spin defects for the γ-irradiated glasses which were absent in the pristine. Optical absorption also changed significantly for the γ-irradiated glasses which exhibited defects-related features around 3.45 and 2.25 eV. The optical band gap and Urbach energies were then determined and compared with those obtained for the γ-irradiated original ISG produced by Mo-SCI Corporation. PL spectroscopy revealed distinct changes after irradiation showing enhanced high-energy emission, contrasting with the γ-irradiated original ISG. The effects of thermal treatment on optical properties of γ-irradiated glasses were finally evaluated. Potential causes at the origin of the contrasting results are discussed based on the effects of different impurities.