Synthesis of high-specific-surface-area Li-Al mixed metal oxide: Through nanoseed-assisted growth of layered double hydroxide

• DOI: 10.1016/j.clay.2021.106006
• Publication Date: 2021-02-18T03:03:58Z
• Authors: Masanori Takemoto; Yasuaki Tokudome; Hidenobu Murata; Kenji Okada; Masahide Takahashi; Atsushi Nakahira
• Keywords: Layered double hydroxides; Specific surface area; Base (topology)

Abstract Li-Al layered double hydroxide (LDH) and LDH-derived mixed metal oxide (MMO) are promising solid base catalysts due to their instinct and strong surface basicity. Herein, nano Li-Al LDH was synthesized via the crystal growth from metal hydroxide nanoseeds with low crystallinities. The present Li-Al LDH possesses high specific surface area (326 m2 g−1), highly crystalline, and high purity. The present nano LDH undergoes a transformation to Li-Al MMO with a high specific surface area (349 m2 g−1) of abundant strong basic sites. Indeed, the present Li-Al MMO exhibits an enhanced catalytic activity for a transesterification reaction between methanol and soybean oil compared to one prepared through a co-precipitation method, thanks to the larger amount of active sites.