Mechanofluorochromism of NIR-emitting dyes based on difluoroboron β-carbonyl cyclic ketonate complexes

• DOI: 10.1016/j.dyepig.2018.03.069
• Publication Date: 2018-03-29T14:51:36Z
• Authors: Fushuang Zhang; Lu Zhai; Siwei Feng; Wenhua Mi; Jingbo Sun; Meng Sun; Jinyu Zhao; Ran Lu
• Keywords: Carbazole; Planarity testing

Abstract New difluoroboron β-carbonyl cyclic ketonate complexes CnB (n = 2, 16), in which carbazole was linked to difluoroboron β-diketonate directly, and DCnB (n = 2, 16), where two terminal carbazole units were bridged by vinyl groups to link to difluoroboron β-diketonate core, were synthesized. They exhibited reversible mechanofluorochromic (MFC) behavior under grinding/fuming or heating treatment. Particularly, the emission of DC2B and DC16B emerged in the range of 650–850 nm in the solid-state. They gave red and rose-red luminescence in the as-synthesized crystals and in the ground powders, respectively, during MFC processes. Such MFC materials emitting NIR (near-infrared) light were seldom reported. In addition, compared with C2B, C16B showed high-contrast mechanofluorochromism because the long alkyl chain might decrease the strength of π-π interactions in the as-synthesized crystals, leading to the emission appeared at the high-energy region (483 nm). The disassembling of parts of π-aggregates and the improvement of the molecular planarity led to red-shift of the emission (509 nm) upon grinding.