A novel strategy to synthesize Au nanoplates and their application for enzymeless H2O2 detection

• DOI: 10.1016/j.electacta.2011.10.066
• Publication Date: 2011-11-03T17:15:10Z
• Authors: Rui Ning; Wenbo Lu; Yingwei Zhang; Xiaoyun Qin; Yonglan Luo; Jianming Hu; Abdullah M. Asiri; Abdulrahman O. Al...; Xuping Sun
• Keywords: Amperometry; Linear range

The present communication reports a novel and simple strategy to synthesize Au nanoplates (AuPs) by heating an aqueous solution of HAuCl 4 in the presence of poly [(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)] (PQ11). Direct placing of the resultant dispersion on a glassy carbon electrode (GCE) surface gives a very stable AuPs-containing film exhibiting remarkable catalytic performance toward both the oxidation and reduction of H 2O 2. This enzymeless H 2O 2 sensor shows a fast amperometric response time of less than 3 s and the corresponding linear range and detection limit are estimated to be from 0.1 mM to 50 mM (r = 0.999) and 4 μM at a signal-to-noise ratio of 3, respectively.