In situ preparation of CuS cathode with unique stability and high rate performance for lithium ion batteries

• DOI: 10.1016/j.electacta.2012.07.004
• Publication Date: 2012-07-16T03:17:06Z
• Authors: Yourong Wang; Xianwang Zhang; Peng Chen; Hantao Liao; Siqing Cheng
• Keywords: 02 engineering and technology; 0210 nano-technology; 7. Clean energy

Abstract A simple approach, for the first time, was presented for in situ preparation of the CuS cathode. The obtained CuS cathodes were investigated by the measurements of X-ray diffraction pattern, scanning electronic microscopy, and electrochemical performance. The results indicate the CuS cathodes are composed of plenty of nano flakes, which construct a large 3-D net structure. Moreover, the CuS cathodes exhibit reversible capacity of 447.4, 414.1, 389.9 and 376.0 mAh g −1 at 0.2 C, 0.5 C, 1 C and 2 C respectively and excellent cycle stability for more than 100 cycles. The possible mechanism of the unique stability of the CuS cathode was discussed.