Size and Structural Effect of Crumpled Graphene Balls on the Electrochemical Properties for Supercapacitor Application

• DOI: 10.1016/j.electacta.2016.11.016
• Publication Date: 2016-11-09T22:17:57Z
• Authors: Eun Hee Jo; Ji-Hyuk Choi; Su-Ryeon Park; Chong Min Lee; Hankwon Chang; Hee Dong Jang
• Keywords: Specific surface area; Power density; Spray pyrolysis

Abstract Effect of size and structure of a three-dimensional (3D) crumpled graphene balls (CGBs) on the electrochemical performance was investigated for supercapacitor application. Different sized CGBs were firstly fabricated by one-step aerosol spray pyrolysis. Electrochemical performance of 3D CGBs for supercapacitor was then measured with respect to size and structural characteristics. The average size of CGBs was controlled in a range of 0.3 to 0.7 μm. CGBs were composed of a few tens of 2D graphene sheets, resulting in different porous structures. CGBs exhibited higher specific surface area and smaller pore volume, and they are composed of micro- and mesopores. The electrochemical performance of supercapacitors fabricated with the as-prepared CGBs, having a different morphology and pore structure, was then evaluated. The maximum specific capacitance of 156 F/g was obtained when 0.7 μm CGBs were employed. In that case, the highest specific energy density and power density were approximately 22 Wh/kg and 4 kW/kg, respectively.