ZnO-based dye-sensitized solar cells: Effects of redox couple and dye aggregation

• DOI: 10.1016/j.electacta.2017.11.075
• Publication Date: 2017-11-13T19:15:49Z
• Authors: Esdras J. Canto-A...; Manuel Rodríguez-...; Rodrigo García-Ro...; Francisco I. Liza...; Alexandra T. De D...; Frank E. Osterloh; Gerko Oskam
• Keywords: Surface Photovoltage; Photocurrent; Triiodide

Abstract The performance of ZnO-based dye-sensitized solar cells (DSSCs) has always been lower than that of TiO2-based devices, however, the factors for this difference are still not entirely understood. Here we use current - voltage curves in combination with intensity-modulated photovoltage spectroscopy, charge extraction measurements, and surface photovoltage spectroscopy to gain insight in the photochemical charge separation in ZnO-based DSSCs. Devices were fabricated with electrodeposited nanostructured, mesoporous ZnO films, an organic fluorenyl-thiophene dye (OD-8) as sensitizer, and an electrolyte solution with either the I−/I3− or [Co(2,2′-bipyridyl)3]2+/3+ redox couple. Surface photovoltage measurements and scanning electron microscopy images show that Zn2+-dye aggregates are most likely the cause of a decrease in cell performance with sensitization times longer than 4 h, due to the relatively acidic acrylonitrile bonding moiety of the OD-8 dye. Charge extraction measurements combined with intensity-modulated photovoltage spectroscopy illustrate that a lower electron lifetime for the DSSCs with the [Co(2,2′-bipyridyl)3]2+/3+ redox couple prevents achieving the thermodynamically attainable photovoltage, thus limiting solar cell efficiency. It can be concluded that further improvements in ZnO-based DSSCs are possible by: (i) avoiding the formation of Zn2+-dye aggregates in the mesoporous structure; (ii) preventing back electron transfer from ZnO to the electron acceptor in the electrolyte solution.