Conductivity in NiSO4–d-glucose–water solutions at 278.15–308.15K

• DOI: 10.1016/j.fluid.2009.06.008
• Publication Date: 2009-06-12T12:49:19Z
• Authors: Kelei Zhuo; Yaohui Liu; Hongxun Liu; Jianji Wang
• Keywords: 02 engineering and technology; 0204 chemical engineering

Abstract Viscosities and densities of d -glucose–water mixtures were measured, and conductivities in the NiSO4– d -glucose–water system were also measured at 278.15–308.15 K in 5 K intervals. Based on the Lee–Wheaton conductivity equation, values of limiting molar conductivities Λ0 and association constants KA were obtained. Changes in the standard thermodynamic functions, Gibbs energy Δ G A ° ( T ) , enthalpy Δ H A ° ( T ) , and entropy Δ S A ° ( T ) , for a process of ion-pair formation were calculated at different temperatures. The results show that (1) at given temperatures, the Λ0 values for 1/2NiSO4 decrease with increasing concentrations of d -glucose; (2) at fixed concentrations of d -glucose, the Λ0 values for 1/2NiSO4 increase with increasing temperature; and (3) the process of association of NiSO4 is controlled by the change in entropy Δ S A ° .