Pulsed laser deposition of bimetallic gold–platinum nanoparticles on cerium oxide and their characterisation by X-ray photoelectron spectroscopy and temperature-programmed desorption of isotopically labelled carbon monoxide

• DOI: 10.1016/j.jcat.2012.11.025
• Publication Date: 2013-01-12T03:36:33Z
• Authors: Jan Plšek; Zdeněk Bastl
• Keywords: Thermal desorption spectroscopy; Bimetallic strip; Thermal desorption; Cerium oxide

Abstract Bimetallic Au–Pt nanoparticles on cerium oxide supports were prepared using pulsed laser deposition (PLD) at room temperature and investigated using X-ray photoelectron spectroscopy (XPS) and temperature-programmed desorption (TPD) of isotopically labelled carbon monoxide 13 C 18 O. The metal deposition caused a partial reduction of Ce 4+ to Ce 3+ . Two components in the spectra of Au (4f) and Pt (4f) photoelectrons were observed and assigned to the charged and metallic state of metals in the nanodeposits. The abundance of the charged species decreased with an increasing amount of the deposited metals and with thermal treatment of the samples. The adsorption properties of the prepared nanodeposits were examined using repeated adsorption–desorption runs of the labelled 13 C 18 O molecules. Carbon monoxide desorbed as 13 C 18 O with a maximum at temperatures ranging from 420 K to 500 K and as 13 C 16 O containing 16 O oxygen exchanged from the supporting oxide at temperatures from 480 to 580 K. The TPD curves from bimetallic Au–Pt nanoparticles differed from those obtained from Pt monometallic deposits by (1) a lower temperature of maximum ( T max ) of the 13 C 16 O desorption peak in the first desorption run and a higher T max of 13 C 18 O for the second desorption, (2) a substantial decrease in the adsorption capacity after repeated adsorption–desorption cycles and (3) stable 13 C 16 O/ 13 C 18 O desorption peak area ratios during repeated adsorption–desorption cycles. Oxidation of CO to CO 2 was observed on all metal deposits on CeO 2− x and also to a lower extent on bare CeO 2− x surfaces. In contrast to the CO desorption, the desorption curves of CO 2 from Pt/CeO 2− x were similar to those from bimetallic Au–Pt nanodeposits.