Interface ion-exchange strategy of MXene@FeIn2S4 hetero-structure for super sodium ion half/full batteries

• DOI: 10.1016/j.jcis.2023.07.071
• Publication Date: 2023-07-16T20:38:02Z
• Authors: Mengqi Wang; Binyang Qin; Shimei Wu; Yining Li; Chilin Liu; Yufei Zhang; Lingxing Zeng; Haosen Fan
• Keywords: Sulfidation; Bimetallic strip

Herein, a well-designed hierarchical architecture of bimetallic transition sulfide FeIn2S4 nanoparticles anchoring on the Ti3C2 MXene flakes has been prepared by cation exchange and subsequent high-temperature sulfidation processes. The introduction of MXene substrate with excellent conductivity not only accelerates the migration rate of Na+ to achieve fast reaction dynamics but provides abundant deposition sites for the FeIn2S4 nanoparticles. In addition, this hierarchical structure of MXene@FeIn2S4 can effectively restrain the accumulation of MXene to guarantee the maximized exposure of redox active sites into the electrolyte, and simultaneously relieve the volume expansion in the repeated discharging/charging processes. The MXene@FeIn2S4 displays outstanding rate capability (448.2 mAh g-1 at 5 A g-1) and stable long cycling performance (428.1 mAh g-1 at 2 A g-1 after 200 cycles). Moreover, the Nay-In6S7 phase detected by ex-situ XRD and XPS characterization may be regarded as a "buffer" to maintain the stability of the Fe-based components and enhance the reversibility of the electrochemical reaction. This work confirms the practicability of constructing the hierarchical structure bimetallic sulfides with the promising electrochemical performance.