Surface-modified composites of metal–organic framework and wood-derived carbon for high-performance supercapacitors

• DOI: 10.1016/j.jcis.2024.09.247
• Publication Date: 2024-10-01T23:58:16Z
• Authors: Wanning Xiong; Linlin Zhao; Jie Ouyang; Yi Tian; Lixin Wang; Mengyao Li; Yuzhu Wang; Mengting Cheng; Qingquan Sheng; Zejun Li; Jianhua Luo; Yongfeng Luo
• Keywords: Carbon fibers

The renewable nature, high carbon content, and unique hierarchical structure of wood-derived carbon make it an optimal self-supporting electrode for energy storage. However, the limitations in specific surface area and electrical conductivity defects pose challenges to achieving satisfactory charge storage in wood-derived carbon electrodes. Therefore, exploring diverse and effective surface strategies is crucial for enhancing the electrochemical energy storage performance. Herein, a decoration technique for enhancing aesthetic appeal involves applying a metal-organic framework (Ni/Co-MOF) containing nickel and cobalt onto the inner walls of wood tracheids. The sequential modification steps include carbonization, oxidation activation, and acid-etching. The Ni/NiO/CoO-CW-4 electrode, made by acid-etching carbonized wood (CW) doped with nickel, nickel oxide, and cobalt oxide for 4 h, has excellent surface area and pore size distribution, high graphitization degree, and exceptional conductivity. Furthermore, surface modification optimizes the surface chemistry and phase composition, resulting in a 0.8 mm thick Ni/NiO/CoO-CW-4 electrode with an exceptionally high areal capacitance of 16.76 F cm-2 at 5 mA cm-2. Meanwhile, the fabricated solid-state supercapacitor achieves an impressive energy density of 0.67 mWh cm-2 (8.38 mWh cm-3) at 2.5 mW cm-2 (31.25 mW cm-3), surpassing representative modified wood-based carbon electrodes by approximately 2-7 times. Additionally, the supercapacitor demonstrates exceptional stability, maintaining 96.21 % of capacitance even over 10,000 cycles. The parameters presented here demonstrate a significant improvement compared to those typically observed in most modified wood-derived carbon-based supercapacitors, effectively addressing common issues of low energy density and suboptimal cycling performance with wood carbon composites.