High homogeneity B1 30.2MHz Nuclear Magnetic Resonance Probe for off-resonance relaxation times measurements

• DOI: 10.1016/j.jmr.2010.10.018
• Publication Date: 2010-11-09T13:21:39Z
• Authors: M. Baranowski; A. Woźniak-Braszak; K. Jurga
• Keywords: Equipment Failure Analysis; Magnetics; Magnetic Resonance Spectroscopy; Transducers; Equipment Design; 01 natural sciences; 0104 chemical sciences

This paper reports on design and construction of a double coil high-homogeneity ensuring Nuclear Magnetic Resonance Probe for off-resonance relaxation time measurements. NMR off-resonance experiments pose unique technical problems. Long irradiation can overheat the sample, dephase the spins because of B(1) field inhomogeneity and degrade the signal received by requiring the receiver bandwidth to be broader than that needed for normal experiment. The probe proposed solves these problems by introducing a separate off-resonance irradiation coil which is larger than the receiver coil and is wound up on the dewar tube that separates it from the receiver coil thus also thermally protects the sample from overheating. Large size of the irradiation coil also improves the field homogeneity because as a ratio of the sample diameter to the magnet (coil) diameter increases, the field inhomogeneity also increases (Blümich et al., 2008) [1]. The small receiver coil offers maximization of the filling factor and a high signal to the noise ratio.