Effect of Al content on the δ→γ transformation and M23C6 precipitation behavior in 18Cr-xAl-Si ferritic heat-resistant stainless steel during solidification process

Diffusionless transformation
DOI: 10.1016/j.jmrt.2022.03.188 Publication Date: 2022-04-06T23:39:23Z
ABSTRACT
Aimed at clarifying δ→γ transformation and M23C6 precipitation behavior in18Cr-xAl-Si (x = 0, 0.43wt.%, 0.91wt.% 1.82wt.%) ferritic heat-resistant stainless steel (FHSS), high temperature confocal scanning laser microscopy (CSLM) was used for in-situ observation during solidification. The results demonstrated that increasing of Al content reduced the nucleation δ-ferrite, same time free energy difference between δ-ferrite γ-austenite, which increased difficulty transformation, in turn transformation. γ-austenite preferentially precipitated phase boundaries gradually along sides as decreased, part martensite transformed inside phases. carbides mainly γ-austenite/martensite. With increase content, amount γ-austenite/martensite decreased. In addition, solidification mechanism complex nucleus also discussed.
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