High-entropy (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3: A promising thermal/environmental barrier material for oxide/oxide composites

• DOI: 10.1016/j.jmst.2020.02.011
• Publication Date: 2020-02-21T09:28:45Z
• Authors: Zifan Zhao; Heng Chen; Huimin Xiang; Fu-Zhi Dai; Xiaohui Wang; Wei Xu; Kuang Sun; Zhijian Peng; Yanchun Zhou
• Keywords: 02 engineering and technology; 0210 nano-technology

Abstract Yttrium aluminum perovskite (YAlO3) is a promising candidate material for environmental barrier coatings (EBCs) to protect Al2O3f/Al2O3 ceramic matrix composites (CMCs) from the corrosion of high-temperature water vapor in combustion environments. Nevertheless, the relatively high thermal conductivity is a notable drawback of YAlO3 for environmental barrier coating application. Herein, in order to make REAlO3 more thermal insulating, a novel high-entropy rare-earth aluminate ceramic (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3 was designed and synthesized. The as-prepared (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3 ceramic possesses close thermal expansion coefficient (9.02 × 10―6 /oC measured from room temperature to 1200 °C) to that of Al2O3. The thermal conductivity of (Y0.2Nd0.2Sm0.2Eu0.2Er0.2) AlO3 at room temperature is 4.1 W·m−1 K−1, which is almost one third of the value of YAlO3. Furthermore, to effectively prevent the penetration of water vapor from possible pores/cracks of coating layer, which are often observed in T/EBCs, a tri-layer EBC system REAlO3/RE3Al5O12/(Al2O3f/Al2O3 CMCs) is designed. Close thermal expansion coefficient to Al2O3 and low thermal conductivity of (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3, as well as the formation of dense garnet layer at (Y0.2Nd0.2Sm0.2Eu0.2Er0.2)AlO3/Al2O3 interface, indicate that this new type of high-entropy ceramic is suitable as a candidate environmental barrier coating material for Al2O3f/Al2O3 CMCs.