Surface modification of soft-templated ordered mesoporous carbon for electrochemical supercapacitors

• DOI: 10.1016/j.micromeso.2015.06.017
• Publication Date: 2015-06-23T05:55:01Z
• Authors: Shunsuke Tanaka; Hiroki Fujimoto; Joeri F.M. Denayer; Manabu Miyamoto; Yasunori Oumi; Yoshikazu Miyake
• Keywords: Double-Layer Capacitance; Water wettability; energy storage; Activated carbon; Performance; Wet oxidation; Ion Storage/Transfer Behavior; Pore Structure; Functional Groups; Hierarchical Porous Carbons; 01 natural sciences; 7. Clean energy; 0104 chemical sciences; Oxygen functionality; Ordered mesoporous carbon; transport; supercapacitor; Electrodes

Abstract The increasing demand for energy has triggered numerous research efforts for the development of electricity storage devices consisting of templated nanoporous carbons. In this study, ordered mesoporous carbon with a modest specific surface area (520 m 2 /g) was prepared by a soft-templating method and surface-modified by a wet oxidation using nitric acid and ammonium peroxodisulfate. More oxygen-containing functional groups were introduced on the surface by oxidation using ammonium peroxodisulfate rather than nitric acid. Our study systematically investigates the effect of surface modification on electrochemical performance, based on comparisons with oxidized commercial activated microporous carbons. Oxygen functionalization leads to an increased capacitance for the ordered mesoporous carbon and a decreased capacitance for the activated microporous carbon at higher power densities. The ordered mesoporous carbon oxidized by nitric acid demonstrates excellent electrochemical performance with gravimetric capacitance of 290 F/g and volumetric capacitance of 300 F/cm 3 at 0.1 A/g and retains over 70% of the capacitance at high current density of 5 A/g even though its surface area remained moderate (430 m 2 /g). The device demonstrates remarkable performance with an energy density of 17.4 Wh/kg, power density of 5.2 kW/kg, and excellent cycle life.