Direct chemical synthesis of ultrathin holey iron doped cobalt oxide nanosheets on nickel foam for oxygen evolution reaction

• DOI: 10.1016/j.nanoen.2018.10.032
• Publication Date: 2018-10-17T20:23:34Z
• Authors: Ying Li; Fu-Min Li; Xin-Ying Meng; Xin-Ru Wu; Shu-Ni Li; Yu Chen
• Keywords: 01 natural sciences; 7. Clean energy; 0104 chemical sciences

Abstract The oxygen evolution reaction (OER) on the anode is a vital electrocatalytic reaction in the field of energy conversion. Currently, transition metals-based nanomaterials are promising Ir/Ru-alternative OER electrocatalysts in alkaline media. In this work, we report that in-situ direct growth of atomically thick Fe doped Co3O4 holey nanosheets on nickel foam (Fe-Co3O4 H-NSs/NF) using a simple cyanogel−NaBH4 route, which effectively avoids the tedious post-etch process of nanosheets using plasma, acid, alkali, and so on. Benefiting from ultrathin thickness (1.5 nm), numerous holes, and synergistic effect between Co and Fe atoms, Fe-Co3O4 H-NSs/NF provide a large specific surface area (199.12 m2 g−1) and highly active catalytic sites for the OER. Meanwhile, nickel foam substrate with three-dimensionally porous structure and high conductivity accelerates molecules/ions/gases transportation and electron transfer. Consequently, Fe-Co3O4 H-NSs/NF with optimal Co/Fe composition show super electrocatalytic performance for the OER, including an overpotential as small as ∼204 mV at 10 mA cm−2 current density and a small Tafel slope of 38 mV dec−1, which is much better than commercial RuO2 nanoparticles.