X-ray radiolysis induced formation of silver nano-particles: A SAXS and UV–visible absorption spectroscopy study

• DOI: 10.1016/j.nimb.2007.06.032
• Publication Date: 2007-07-17T07:18:31Z
• Authors: S. Remita; P. Fontaine; E. Lacaze; Y. Borensztein; H. Sellame; R. Farha; C. Rochas; M. Goldmann
• Keywords: Small-angle X-ray scattering; Silver Nano; Ultraviolet visible spectroscopy

Abstract We show that X-ray irradiation of metal salt aqueous solutions in the absence of any stabilizer leads to the synthesis of metal nano-particles, similarly to γ-ray irradiation. The chemical route is the reduction of silver metal ions induced by radiolysis of water. Moreover, X-rays used for the synthesis allow following in situ the formation of silver nano-particles by Small Angle X-ray Scattering associated with UV–visible absorption spectroscopy. The synthesized nano-objects appear spherical with a radius of about 14 nm.