External-RBS, PIXE and NRA analysis for ancient swords

• DOI: 10.1016/j.nimb.2014.12.076
• Publication Date: 2015-01-13T19:48:25Z
• Authors: Hellen C. Santos; Nemitala Added; Tiago F. Silva; C.L. Rodrigues
• Keywords: Nuclear reaction analysis; Accelerator mass spectrometry; Case hardening; Carbon fibers

Abstract Elemental composition of the steel of two ancient swords (Japanese and Damascus from a private collection) was characterized using in air IBA techniques. Our results contribute for the understanding the processes of manufacturing (hammering and quenching) and surface treatments applied in these swords. The Particle Induced X-ray Emission (PIXE) measurements along the Damascus blade allowed to identify and to trace a superficial concentration profile for the elements such Cr, Mn, Fe, Ni, Cu, Zn and As, while results for the Japanese blade showed only the presence of iron. The carbon content on the surface was also investigated using a resonant region in the Elastic Backscattering Spectrometry (EBS) measurements and the results have shown a slightly difference between the surfaces under investigation. In order to investigate the nitrogen content on surface, that could explain the hardening process, we used Nuclear Reaction Analysis (NRA) and the results shown that nitrogen content was under our detection limit for the technique (0.3% in mass). The measurements of PIXE, NRA and EBS were taken using the external beam setup installed at Lamfi – Sao Paulo/Brazil, the latter being successfully implemented for the first time in this facility.