Structure and ion transport in an ethylene carbonate-modified biodegradable gel polymer electrolyte

• DOI: 10.1016/j.polymertesting.2016.12.014
• Publication Date: 2016-12-23T13:31:31Z
• Authors: Ravi Muchakayala; Shenhua Song; Shang Gao; Xiaoling Wang; Youhua Fan
• Keywords: 02 engineering and technology; 0210 nano-technology; 3. Good health

Abstract The influence of ethylene carbonate (EC) addition on 85poly(e-caprolactone):15Lithium thiocyanate (85PCL:15LiSCN) polymer electrolyte is investigated using X-ray diffraction, impedance spectroscopy, Wagner's polarization and electrochemical measurements. The results reveal that the amorphicity of the 85PCL:15LiSCN system increases with increase of EC content up to an optimal level of 40 wt.%. This is reflected in the electrical properties of the gel polymer electrolytes, i.e., the 40 wt.% EC-incorporated gel polymer electrolyte exhibits both high amorphicity and high electrical conductivity as compared to the other samples. The EC concentration dependences of dielectric constant and electrical conductivity show a similar trend, indicating that these properties are closely related to each other. The total ionic transference numbers of EC-incorporated gel polymer electrolytes are in the range 0.989–0.993, demonstrating that they are almost completely ionic conductors. The electrochemical stability window of the 40 wt.% EC-incorporated gel polymer electrolyte is ∼4.1 V along with the electrical conductivity of 2.2 × 10−4 S cm−1, which is significantly improved as compared to the 85PCL:15LiSCN system (3.0 V and 1.04 × 10−6 S cm−1). Consequently, the addition of EC in the 85PCL:15LiSCN polymer electrolyte leads to a promising improvement in its various properties.