A methacryl ethyl-functionalized soluble polypyrrole: Synthesis, characterization, and potentiality in rapid fabrication of high-aspect-ratio pillar arrays

• DOI: 10.1016/j.reactfunctpolym.2016.12.005
• Publication Date: 2016-12-06T17:00:52Z
• Authors: Guowei Lv; Shihu Zhang; Guolong Wang; Jinyou Shao; Hongmiao Tian; Demei Yu
• Keywords: Polypyrrole; Photoresist

Abstract A methacryl ethyl-functionalized soluble polypyrrole was designed and prepared by chemical oxidative polymerization for rapid fabrication of high-aspect-ratio pillar arrays. The chemical structures of the pyrrole derivative and the corresponding polypyrrole were characterized by FTIR and 1H NMR. The polypyrrole with a weight-average molecular weight (Mw) of 7376 exhibits good solubility in several organic solvents, favorable thin film-forming ability and two UV–Vis absorption peaks at 280 and 380 nm in tetrahydrofuran solution. The dilute chloroform solution of the polypyrrole is a Newtonian fluid with a low viscosity and shows a significant increase in the electrical conductivity with increasing the polypyrrole content. Moreover, an insulating photoresist can be transformed into a conductive photoresist by doping this polypyrrole. Electrowetting driven structure formation experiments have confirmed that the conductive photoresist can fulfill rapid fabrication of higher-aspect-ratio pillar arrays compared with the insulating photoresist.