Synthesis and characterization of new thienylpyrrolyl-benzothiazoles as efficient and thermally stable nonlinear optical chromophores

• DOI: 10.1016/j.tet.2007.03.065
• Publication Date: 2007-03-15T10:55:26Z
• Authors: Rosa M.F. Batista; Susana P.G. Costa; Elisabeth L. Malh...; Michael Belsley; M. Manuela M. Raposo
• Keywords: Solvatochromism; Chromophore; Thermogravimetric analysis; Thermal Stability; Hyperpolarizability; Characterization

Abstract The synthesis and full characterization of new chromophores with second-order nonlinearities containing thienylpyrrolyl and benzothiazolyl moieties are reported. The solvatochromic behavior of the compounds was investigated. The hyperpolarizabilities β of derivatives 4 – 6 were measured using hyper-Rayleigh scattering and thermogravimetric analysis (TGA) was used to evaluate their thermal stability. The experimental results indicate that strong nonlinearity is balanced by good thermal stability especially for chromophores 6b and 6c , making them good candidates for NLO applications.