Recent Advances in Titanium Radical Redox Catalysis

• DOI: 10.1021/acs.joc.9b02465
• Publication Date: 2019-10-24T23:26:51Z
• Authors: Terry McCallum; Xiangyu Wu; Song Lin
• Keywords: Leverage (statistics)

New catalytic strategies that leverage single-electron redox events have provided chemists with useful tools for solving synthetic problems. In this context, Ti offers opportunities are complementary to late transition metals reaction discovery. Following foundational work on epoxide reductive functionalization, recent methodological advances significantly expanded the repertoire of radical chemistry. This Synopsis summarizes developments in burgeoning area catalysis a focus innovative such as redox-relay and dual catalysis.