Cu(I)-Catalyzed Tandem Reaction of Carbene Coupling and Horner–Wadsworth–Emmons Type Olefination: Access toward Enynes

• DOI: 10.1021/acs.orglett.6b00631
• Publication Date: 2016-04-26T13:10:47Z
• Authors: Yujing Zhou; Fei Ye; Qi Zhou; Yan Zhang; Jianbo Wang
• Keywords: 01 natural sciences; 0104 chemical sciences

AbstractThe efficient one‐pot three component reaction between aryl αdiazophosphonates, (triisopropylsilyl)acetylene and aryl, hetaryl, alkenyl or alkyl aldehydes proceeds with high to excellent (Z)‐selectivity.