Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts

• DOI: 10.1021/jacs.5b03937
• Publication Date: 2015-06-19T13:30:43Z
• Authors: Elise Cahard; Henry P. J. Male; Matthieu Tissot; Matthew J. Gaunt
• Keywords: Stereoisomerism; Amides; Hydrocarbons, Aromatic; 01 natural sciences; Catalysis; 0104 chemical sciences; Allyl Compounds; Onium Compounds; Oxazines; Oxazoles; Copper

Abstract3‐Aryl substituted (2Z)‐prop‐2‐en‐1‐ylamides are transformed in the presence of a chiral copper‐bisoxazoline catalyst with diaryliodonium salts.