Giant Piezoelectricity and High Curie Temperature in Nanostructured Alkali Niobate Lead-Free Piezoceramics through Phase Coexistence

• DOI: 10.1021/jacs.6b09024
• Publication Date: 2016-11-17T20:38:51Z
• Authors: Bo Wu; Haijun Wu; Jiagang Wu; Dingquan Xiao; Jianguo Zhu; Stephen J. Pennycook
• Keywords: 02 engineering and technology; 0210 nano-technology

Because of growing environmental concerns, the development of lead-free piezoelectric materials with enhanced properties has become of great interest. Here, we report a giant piezoelectric coefficient (d33) of 550 pC/N and a high Curie temperature (TC) of 237 °C in (1-x-y)K1-wNawNb1-zSbzO3-xBiFeO3-yBi0.5Na0.5ZrO3 (KNwNSz-xBF-yBNZ) ceramics by optimizing x, y, z, and w. Atomic-resolution polarization mapping by Z-contrast imaging reveals the intimate coexistence of rhombohedral (R) and tetragonal (T) phases inside nanodomains, that is, a structural origin for the R-T phase boundary in the present KNN system. Hence, the physical origin of high piezoelectric performance can be attributed to a nearly vanishing polarization anisotropy and thus low domain wall energy, facilitating easy polarization rotation between different states under an external field.