Ultrafast Dynamics of Surface Plasmons in InAs by Time-Resolved Infrared Nanospectroscopy

• DOI: 10.1021/nl501558t
• Publication Date: 2014-07-21T14:56:33Z
• Authors: Martin Wagner; Alexander S. McLeod; Scott J. Maddox; Zhe Fei; Mengkun Liu; Richard D. Averitt; Michael M. Fogler; Seth R. Bank; Fritz Keilmann; D. N. Basov
• Keywords: s-SNOM; 02 engineering and technology; semiconductor; Physical Chemistry; ultrafast spectroscopy; pump-probe; Surface plasmon; Physical Sciences; Chemical Sciences; Nanoscience & Nanotechnology; 0210 nano-technology; near-field microscopy

We report on time-resolved mid-infrared (mid-IR) near-field spectroscopy of the narrow bandgap semiconductor InAs. The dominant effect we observed pertains to the dynamics of photoexcited carriers and associated surface plasmons. A novel combination of pump-probe techniques and near-field nanospectroscopy accesses high momentum plasmons and demonstrates efficient, subpicosecond photomodulation of the surface plasmon dispersion with subsequent tens of picoseconds decay under ambient conditions. The photoinduced change of the probe intensity due to plasmons in InAs is found to exceed that of other mid-IR or near-IR media by 1-2 orders of magnitude. Remarkably, the required control pulse fluence is as low as 60 μJ/cm(2), much smaller than fluences of ∼ 1-10 mJ/cm(2) previously utilized in ultrafast control of near-IR plasmonics. These low excitation densities are easily attained with a standard 1.56 μm fiber laser. Thus, InAs--a common semiconductor with favorable plasmonic properties such as a low effective mass--has the potential to become an important building block of optically controlled plasmonic devices operating at infrared frequencies.