Semiconductive microporous hydrogen-bonded organophosphonic acid frameworks

• DOI: 10.1038/s41467-020-16977-0
• Publication Date: 2020-06-23T10:03:35Z
• Authors: Patrik Tholen; Craig A. Peeples; Raoul Schaper; Ceyda Bayraktar; Turan Selman Erkal; Mehmet Menaf Ayhan; Bünyemin Çoşut; Jens Beckmann; A. Ozgur Yazaydin; Michael Wark; Gabriel Hanna; Yunus Zorlu; Gündoğ Yücesan
• Keywords: materials science; Science; Q; hydrogen-bonded organic framework; 01 natural sciences; Materials science; Article; 0104 chemical sciences; Chemistry; 540 Chemie und zugeordnete Wissenschaften; HOF; ddc:540

Herein, we report a semiconductive, proton-conductive, microporous hydrogen-bonded organic framework (HOF) derived from phenylphosphonic acid and 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin (GTUB5). The structure of GTUB5 was characterized using single crystal X-ray diffraction. A narrow band gap 1.56 eV extracted UV-Vis spectrum pure crystals, in excellent agreement with the 1.65 obtained DFT calculations. same also measured for DMSO. proton conductivity to be 3.00 × 10