Chiral magnetic metal–organic frameworks of MnII with achiral tetrazolate-based ligands by spontaneous resolution

• DOI: 10.1039/c0cc03111a
• Publication Date: 2010-10-19T13:30:24Z
• Authors: Xiao-Lan Tong; Tong-Liang Hu; Jiong-Peng Zhao; Yue-Kui Wang; Hui Zhang; Xian-He Bu
• Keywords: Chiral resolution

The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence a chiral source. enantiomeric nature 1a 1b was confirmed circular dichroism (CD) spectra theoretical investigation.