A 12-connected metal–organic framework constructed from an unprecedented cyclic dodecanuclear copper cluster

• DOI: 10.1039/c2cc32120c
• Publication Date: 2012-06-07T14:01:38Z
• Authors: Huan Zhang; Ying Lu; Zhiming Zhang; Hai Fu; Yangguang Li; Dirk Volkmer; Dmytro Denysenko; Enbo Wang
• Keywords: ddc:530; 01 natural sciences; 0104 chemical sciences

A 12-connected metal-organic framework based on an unprecedented cyclic Cu(12) cluster with a large internal cavity has been prepared, and its cation exchange property was determined.