Pyridine-2-thiolate bridged tin–palladium complexes with Sn(PdN2Cl2), Sn(PdN2S2), Sn(PdN2C2) and Sn(Pd2N4) skeletons

• DOI: 10.1039/c3cc47912a
• Publication Date: 2013-12-03T10:05:30Z
• Authors: Erik Wächtler; Robert Gericke; Lyuben Zhechkov; Thomas Heine; Thorsten Langer; Birgit Gerke; Rainer Pöttgen; Jörg Wagler
• Keywords: 01 natural sciences; 0104 chemical sciences

Reactions of tin(IV) complexes the type Sn(PyS)2X2 (X = Cl, PyS, Ph; PyS pyridine-2-thiolate) with Pd(PPh3)4 provide easy access to novel heterometallic Pd–Sn bonds. Electronic characteristics this connection were analysed by X-ray crystallography, 119Sn Mössbauer spectroscopy and quantum chemical analyses.