Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co(iii) and subsequent Co(i)/Co(iii) comproportionation

• DOI: 10.1039/d0sc01813a
• Publication Date: 2020-05-19T22:05:10Z
• Authors: Bryan J. Foley; Chandra Mouli Palit; Nattamai Bhuvanesh; Jia Zhou; Oleg V. Ozerov
• Keywords: Chemistry; 01 natural sciences; 0104 chemical sciences

This report discloses a combined experimental and computational study aimed at understanding C–S reductive elimination from Co(iii) supported by a diarylamido/bis(phosphine) PNP pincer ligand.