“Bottled” spiro-doubly aromatic trinuclear [Pd2Ru]+complexes

• DOI: 10.1039/d0sc04469e
• Publication Date: 2020-10-23T15:23:57Z
• Authors: Maksim Kulichenko; Nikita Fedik; Anna Monfredini; Alvaro Muñoz-Castro; Davide Balestri; Alexander I. Bold...; Giovanni Maestri
• Keywords: Chemistry; Settore CHEM-03/A - Chimica generale e inorganica; metal-metal bond; cluster compounds; Settore CHEM-05/A - Chimica organica; aromaticity; palladium; ruthenium; 540; 01 natural sciences; 0104 chemical sciences

Synthesis of a triangular [Pd2Ru]+complex with delocalized metal–metal bonding between non-adjacent elements of the periodic table, double aromaticity and overlap of d-AOs with different angular momentum.